№ files_lp_4_process_2_73134
Scientific research article describing the synthesis and characterization of a tetrahedral Zn4L4 coordination cage that forms a permanently porous ionic liquid capable of encapsulating chlorofluorocarbons and selectively binding alcohol isomers based on molecular size and shape.
Authors: Lillian Ma; Cally J. E. Haynes; Angela B. Grommet; Anna Walczak; Christopher C. Parkins; Cara M. Doherty; Louis Longley; Arnaud Tron; Artur R. Stefankiewicz; Thomas D. Bennett; Jonathan R. Nitschke
Affiliated institutions: University of Cambridge; University College London; Adam Mickiewicz University; Commonwealth Scientific and Industrial Research Organisation
Academic field: Chemistry; Materials Science
Research area: Porous liquids and coordination cages
Type of document: Scientific research article
Studied materials: Tetrahedral Zn4L4 coordination cage; PEG-imidazolium functionalised cages
Chemical compounds mentioned: Trichlorofluoromethane (CFC-11); Dichlorodifluoromethane (CFC-12); Chlorotrifluoromethane (CFC-13); Butanol and propanol isomers
Methodology: Synthesis of coordination cages; NMR spectroscopy; rheological analysis
Temperature conditions studied: 25–100 °C
State of material: Ionic liquid with permanent porosity
Guest molecules investigated: Chlorofluorocarbons and alcohol isomers
Scientific focus: Molecular encapsulation and size- and shape-selective binding in porous liquids
Corresponding authors: Thomas D. Bennett; Jonathan R. Nitschke
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