№ files_lp_4_process_1_26861
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Supplementary scientific material presenting experimental procedures, synthesis, spectroscopic characterization, crystallographic data, and catalytic hydroformylation results for the cobalt complex [CoH(dchpf)(CO)2] in reactions with 1-octene.
Document type: Scientific supporting information
Scientific field: Inorganic chemistry; organometallic catalysis
Research topic: Hydroformylation of 1-octene using a cobalt hydride complex
Related research article: Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)2]
Authors: Alexander Marco Kluwer; Michael J. Krafft; Ingo Hartenbach; Bas de Bruin; Wolfgang Kaim
Affiliations: InCatT B.V., Amsterdam; Universität Stuttgart, Institut für Anorganische Chemie; Van ’t Hoff Institute for Molecular Sciences, Universiteit van Amsterdam
Country: Netherlands; Germany
Compounds studied: [CoH(dchpf)(CO)2]; octacarbonyldicobalt; 1-octene
Experimental techniques: 1H-NMR spectroscopy; 31P-NMR spectroscopy; infrared spectroscopy; cyclic voltammetry; gas chromatography; X-ray crystallography
Instrumentation: Bruker AC 250 NMR spectrometer; Nicolet 6700 FT-IR spectrometer; PAR 273 potentiostat; Shimadzu GC Ultra with ChirasilDex CB column; Nonius Kappa CCD diffractometer; AMTEC SPR16 parallel autoclave system
Catalytic system: Cobalt complex [CoH(dchpf)(CO)2]
Reaction type: Hydroformylation under syngas (CO/H2) atmosphere
Substrate: 1-octene
Solvent: Toluene
Reaction atmosphere: Nitrogen and syngas (CO/H2 = 1:1)
Experimental conditions: Temperatures 100–170 °C; pressures 10–40 bar
Reaction time: 21 hours
Analytical data: NMR spectra, IR spectra, electrochemical data, crystallographic parameters, gas-uptake curves
Crystallographic system: Monoclinic, space group P21/c
Empirical formula of studied complex: C36H52CoFeO2P2
Molecular weight: 693.50
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