№ files_lp_3_process_7_103357
Laboratory experiment protocol describing the kinetic measurement of the thermal back reaction of the merocyanine isomer of 6-NO2-BIPS in toluene using temperature-dependent transient absorption spectroscopy and Arrhenius analysis.
Subject: Physical Chemistry
Topic: Photochromism and Reaction Kinetics
Molecule: 1’,3’-dihydro-1’,3’,3’-trimethyl-6-nitrospiro(2H-1-benzopyran-2,2’-2H-indole) (6-NO2-BIPS)
Chemical System: Spiropyran in Toluene Solution
Experiment Type: Laboratory Experiment
Method: Flash Photolysis Spectroscopy
Observation Wavelength: 600 nm
Excitation Wavelength: <400 nm
Temperature Range: 30–60 °C
Measured Parameter: Lifetime (τ) of Thermal Back Reaction
Calculated Parameter: Activation Energy (Ea)
Theoretical Model: Arrhenius Equation
Reported Literature Value: 62.5 kJ mol-1
Software Used: Logger Pro
Intended Level: Undergraduate Laboratory
Price: 8 / 10 USD
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